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The main difference is that Pea Protein is Vegan and Whey Protein Isolate is not.
WPI forms part of the cheesemaking process and is purified through complex procedures to create the powder.
Pea Protein is made from dried field peas and is refined to extract all of the protein nutrients which are then formed into a powder.
Both WPI and Pea Protein contain important BCAAs which support muscle repair and recovery.